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The influence of curing conditions on the mechanical properties and leaching of inorganic polymers made

Remus I. Iacobescu, Valérie Cappuyns, Tinne Geens, Lubica Kriskova, Silviana Onisei, Peter T. Jones, Yiannis Pontikes

《化学科学与工程前沿（英文）》 2017年 第11卷 第3期   页码 317-327 doi: 10.1007/s11705-017-1622-6

摘要： This study reports on the impact of the curing conditions on the mechanical properties and leaching of inorganic polymer (IP) mortars made from a water quenched fayalitic slag. Three similar IP mortars were produced by mixing together slag, aggregate and activating solution, and cured in three different environments for 28 d: a) at 20 °C and relative humidity (RH) ~ 50% (T20RH50), b) at 20 °C and RH≥90% (T20RH90) and c) at 60 °C and RH ~ 20% (T60RH20). Compressive strength (EN 196-1) varied between 19 MPa (T20RH50) and 31 MPa (T20RH90). This was found to be attributed to the cracks formed upon curing. Geochemical modelling and two leaching tests were performed, the EA NEN 7375 tank test, and the BS EN 12457-1 single batch test. Results show that Cu, Ni, Pb, Zn and As leaching occurred even at high pH, which varied between 10 and 11 in the tank test’s leachates and between 12 and 12.5 in the single batch’s leachates. Leaching values obtained were below the requirements for non-shaped materials of Flemish legislation for As, Cu and Ni in the single batch test.

关键词： inorganic polymer     geochemical leaching modelling     heavy metals     recycling     non-ferrous fayalitic slag     curing    

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Sequence of the main geochemical controls on the Cu and Zn fractions in the Yangtze River estuarine sediments

Shou ZHAO,Dongxin WANG,Chenghong FENG,Ying WANG,Zhenyao SHEN

《环境科学与工程前沿（英文）》 2016年 第10卷 第1期   页码 19-27 doi: 10.1007/s11783-014-0723-4

摘要： Metal speciation can provide sufficient information for environmental and geochemical researches. In this study, based on the speciation determination of Cu and Zn in the Yangtze Estuary sediments, roles of eight geochemical controls (i.e., total organic carbon (TOC), clay, Fe/Mn in five chemical fractions and salinity) are fully investigated and sequenced with correlation analysis (CA) and principal components analysis (PCA). Results show that TOC, clay and Fe/Mn oxides are key geochemical factors affecting the chemical speciation distributions of Cu and Zn in sediments, while the role of salinity appears to be more indirect effect. The influencing sequence generally follows the order: TOC>clay>Mn oxides>Fe oxides>salinity. Among the different fractions of Fe/Mn oxides, residual and total Fe content, and exchangeable and carbonate Mn exert the greatest influences, while exchangeable Fe and residual Mn show the poorest influences.

关键词： chemical speciation     geochemical factors     estuaries     sediments     correlation     salinity    

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Characteristics of the stabilized/solidified municipal solid wastes incineration fly ash and the leaching

Yan SHAO,Haobo HOU,Guangxing WANG,Sha WAN,Min ZHOU

《环境科学与工程前沿（英文）》 2016年 第10卷 第1期   页码 192-200 doi: 10.1007/s11783-014-0719-0

摘要： Fly ash is a hazardous byproduct of municipal solid wastes incineration (MSWI). An alkali activated blast furnace slag-based cementitious material was used to stabilize/solidify the fly ash at experimental level. The characteristics of the stabilized/solidified fly ash, including metal leachability, mineralogical characteristics and the distributions of metals in matrices, were tested by toxic characteristic leaching procedure (TCLP), X-ray diffraction (XRD) and scanning electron microscopy-energy dispersive spectrometer (SEM-EDS) respectively. Continuous acid extraction was utilized to extract metal ions and characterize their leaching behavior. The stabilization/solidification procedure for MSWI fly ash demonstrates a strong fixing capacity for the metals by the formation of C-S-H phase, hydrated calcium aluminosilicate and ettringite. The stabilized/solidified fly ash shows a dense and homogeneous microstructure. Cr is mainly solidified in hydrated calcium aluminosilicate, C-S-H and ettringite phase through physical encapsulation, precipitation, adsorption or substitution mechanisms, and Pb is mainly solidified in C-S-H phase and absorbed in the Si-O structure.

关键词： municipal solid waste incineration (MSWI) fly ash     blast furnace slag     leaching behavior     Cr     Pb    

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Assessment of leaching behavior and human bioaccessibility of rare earth elements in typical hospital

Chunfeng Wang, Guanfei Chen, Yanchen Zhu, Dan Yao, Wanfeng Wang, Lianjun Wang

《环境科学与工程前沿（英文）》 2017年 第11卷 第6期 doi: 10.1007/s11783-017-0946-2

摘要： Leaching behavior and gastrointestinal bioaccessibility of rare earth elements (REEs) from hospital waste incineration (HWI) fly and bottom ash samples collected from Beijing and Nanjing Cities were assessed. In the same ash sample, the leaching concentrations of individual REEs determined by the Toxicity Characteristic Leaching Procedure (TCLP) were higher than those detected by the European standard protocol (EN-type test), thereby suggesting that the low pH value of leaching solution was an important factor influencing the leachability of REE. The REE bioaccessibility results, which were evaluated using the physiologically based extraction test (PBET), indicated that REEs were highly absorbed during gastric phase by dissolution; and subsequently precipitated and/or re-adsorbed in small intestinal phase. The relative amounts of the total REEs extracted by the TCLP method, EN-type test and PBET test were compared. In addition to the pH value of extraction solutions, the chelating role of REEs with organic ligands used in the PBET method was also an important parameter affecting REE adsorption in human body. Additionally, this study showed that REEs were extracted by these methods as concomitants of heavy metals and anions (NO , F , SO , and Cl ) from HWI ash, which probably caused the remarkably complex toxicity on human body by the exposure pathway.

关键词： Assessment     Rare earth elements     Leaching behavior     Bioaccessibility     Hospital waste    

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Understanding coupled factors that affect the modelling accuracy of typical planar compliant mechanisms

Guangbo HAO,Haiyang LI,Suzen KEMALCAN,Guimin CHEN,Jingjun YU

《机械工程前沿（英文）》 2016年 第11卷 第2期   页码 129-134 doi: 10.1007/s11465-016-0392-z

摘要：

In order to accurately model compliant mechanism utilizing plate flexures, qualitative planar stress (Young’s modulus) and planar strain (plate modulus) assumptions are not feasible. This paper investigates a quantitative equivalent modulus using nonlinear finite element analysis (FEA) to reflect coupled factors in affecting the modelling accuracy of two typical distributed-compliance mechanisms. It has been shown that all parameters have influences on the equivalent modulus with different degrees; that the presence of large load-stiffening effect makes the equivalent modulus significantly deviate from the planar assumptions in two ideal scenarios; and that a plate modulus assumption is more reasonable for a very large out-of-plane thickness if the beam length is large.

关键词： coupling factors     modelling accuracy     compliant mechanisms     equivalent modulus    

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Investigation of Cu leaching from municipal solid waste incinerator bottom ash with a comprehensive approach

Jun YAO, Wenbing LI, Fangfang XIA, Jing WANG, Chengran FANG, Dongsheng SHEN

《能源前沿（英文）》 2011年 第5卷 第3期   页码 340-348 doi: 10.1007/s11708-010-0131-9

摘要： Municipal solid waste incinerator (MSWI) bottom ash is often reused as a secondary construction material. This study used a comprehensive approach to characterize the leaching behavior of copper (Cu) from the MSWI bottom ash. The batch titration procedure was used to determine the acid neutralizing capacity and Cu leaching as a function of pH. The sequential extraction procedure (SEP) was adopted to analyze the speciation of Cu in the MSWI bottom ash. The metal speciation equilibrium model for surface and ground water (Visual MINTEQ) was used to evaluate the equilibrium of the leachates with the relative minerals, and to determine the speciation of the aqueous Cu in the leachates. Based on the multi-analysis of the results, Cu would be significantly released from the MSWI bottom ash when it is acidic. The Cu leaching pattern was not only affected by dissolved organic carbon, it was also limited by its speciation in the MSWI bottom ash. Furthermore, almost 100% of the aqueous Cu in the leachate was bound to organic matter in basic and neutral conditions, but mostly existed as Cu in an acidic condition. These findings provide an important insight into predicting the leaching behavior of Cu from the MSWI bottom ash, as well as its impact on the environment.

关键词： MSWI bottom ash     Cu leaching     batch titration procedure     SEP    

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Reinforcement of the two-stage leaching of laterite ores using surfactants

Peiyu Zhang, Hairui Wang, Jingcheng Hao, Jiwei Cui

《化学科学与工程前沿（英文）》 2021年 第15卷 第3期   页码 562-570 doi: 10.1007/s11705-020-1946-5

摘要： A two-stage leaching process, namely, high-pressure acid leaching-atmospheric acid leaching, was used to treat laterite ores under mild conditions. The leaching ratio of Ni was low because of adsorption and incomplete leaching. In this work, surfactants were used as additives to boost the leaching ratio of Ni. The effect of surfactant type (cationic, anionic, and nonionic surfactants) on the leaching ratio of Ni was investigated. Leaching results showed that stearyl trimethyl ammonium chloride (STAC) apparently increased the leaching ratios of valuable metals. The variation in the physicochemical properties of the lixiviant and the residue improved the leaching ratio of Ni in the presence of STAC. Kinetics analysis indicated that the leaching process was controlled by chemical reaction.

关键词： laterite ore     Ni     surfactant     acid leaching    

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Oxidative leaching kinetics of molybdenum-uranium ore in H

T. A. Lasheen, M. E. El-Ahmady, H. B. Hassib, A. S. Helal

《化学科学与工程前沿（英文）》 2013年 第7卷 第1期   页码 95-102 doi: 10.1007/s11705-013-1317-6

摘要： The processing of molybdenum-uranium ore in a sulfuric acid solution using hydrogen peroxide as an oxidant has been investigated. The leaching temperature, hydrogen peroxide concentration, sulfuric acid concentration, leaching time, particle size, liquid-to-solid ratio and agitation speed all have significant effects on the process. The optimum process operating parameters were: temperature: 95°C; H O concentration: 0.5 M; sulfuric acid concentration: 2.5 M; time: 2 h; particle size: 74 μm, liquid-to-solid ratio: 14 ∶ 1 and agitation speed: 600 rpm. Under these experimental conditions, the extraction efficiency of molybdenum was about 98.4%, and the uranium extraction efficiency was about 98.7%. The leaching kinetics of molybdenum showed that the reaction rate of the leaching process is controlled by the chemical reaction at the particle surface. The leaching process follows the kinetic model 1 ? (1? ) = with an apparent activation energy of 40.40 kJ/mole. The temperature, concentrations of H O and H SO and the mesh size are the main factors that influence the leaching rate. The reaction order in H SO was 1.0012 and in H O it was 1.2544.

关键词： leaching of molybdenum     leaching of uranium     kinetics    

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3D fracture modelling and limit state analysis of prestressed composite concrete pipes

Pengfei HE, Yang SHEN, Yun GU, Pangyong SHEN

《结构与土木工程前沿（英文）》 2019年 第13卷 第1期   页码 165-175 doi: 10.1007/s11709-018-0484-4

摘要： In this manuscript, we study fracture of prestressed cylindrical concrete pipes. Such concrete pipes play a major role in tunneling and underground engineering. The structure is modelled fully in 3D using three-dimensional continuum elements for the concrete structure which beam elements are employed to model the reinforcement. This allows the method to capture important phenomena compared to a pure shell model of concrete. A continuous approach to fracture is chosen when concrete is subjected to compressive loading while a combined continuous-discrete fracture method is employed in tension. The model is validated through comparisons with experimental data.

关键词： cylindrical concrete structures     limit state analysis     3D fracture modelling     prestressed composite pipes     reinforced concrete     three-point bending test    

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铜阳极泥预处理连续加压酸浸工艺开发研究

王吉坤,冯桂林

《中国工程科学》 2009年 第11卷 第5期   页码 18-22

摘要：

绍了新开发出来的一种具有较好工业应用前景的铜阳极泥预处理新工艺，小型及半工业试验结果表明，铜阳极泥直接加压酸浸，可以充分利用生阳极泥中水溶性铜离子的催化氧化作用，提高反应速度；在连续浸出过程中Ag，Se，Te走向与间断浸出过程差别明显，使浸出效果优于间断加压浸出预处理工艺，有利于提高有价元素的综合回收。

关键词： 铜阳极泥     综合利用     加压酸浸     连续浸出    

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ANN-based empirical modelling of pile behaviour under static compressive loading

Abdussamad ISMAIL

《结构与土木工程前沿（英文）》 2018年 第12卷 第4期   页码 594-608 doi: 10.1007/s11709-017-0446-2

摘要： Artificial neural networks have been widely used over the past two decades to successfully develop empirical models for a variety of geotechnical problems. In this paper, an empirical model based on the product-unit neural network (PUNN) is developed to predict the load-deformation behaviour of piles based SPT values of the supporting soil. Other parameters used as inputs include particle grading, pile geometry, method of installation as well as the elastic modulus of the pile material. The model is trained using full-scale pile loading tests data retrieved from FHWA deep foundations database. From the results obtained, it is observed that the proposed model gives a better simulation of pile load-deformation curves compared to the Fleming’s hyperbolic model and t-z approach.

关键词： piles in compression     load-deformation behaviour     product-unit neural network    

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Leaching of aluminum from coal spoil by mechanothermal activation

Xiaoxue SUN,Yuzhu SUN,Jianguo YU

《化学科学与工程前沿（英文）》 2015年 第9卷 第2期   页码 216-223 doi: 10.1007/s11705-015-1518-2

摘要： The process of activating coal spoil (CS) in order to recover aluminum as a high value product was investigated. The CS was first characterized by X-ray fluorescence (XRF), X-ray diffraction (XRD) and thermogravimetric analysis-differential scanning calorimetry (TGA-DSC) in order to determine the chemical and mineral compositions of the CS. Then a mechanothermal activation method was adopted to increase the aluminum activity in the coal spoil. Over 95% of the aluminum in the CS could be extracted using this activation method. The mechanothermal activation process promoted the destruction of kaolinite structures and hindered the formation of amorphous -Al O . This resulted in a high aluminum leaching activity in the mechanothermally activated CS.

关键词： coal spoil     mechanothermal compound activation     leaching    

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Kinetic-compartmental modelling of potassium-containing cellulose feedstock gasification

Attila Egedy, Lívia Gyurik, Tamás Varga, Jun Zou, Norbert Miskolczi, Haiping Yang

《化学科学与工程前沿（英文）》 2018年 第12卷 第4期   页码 708-717 doi: 10.1007/s11705-018-1767-y

摘要：

Biomass is of growing interest as a secondary energy source and can be converted to fuels with higher energy density especially by pyrolysis or gasification. Understanding the mechanism and the kinetics of biomass pyrolysis (thermal decomposition) and gasification (conversion of organic material to gases) could be the key to the design of industrial devices capable of processing vast amounts of biomass feedstock. In our work real product components obtained in pyrolysis were took into consideration as well as char and oil as lumped components, and the kinetic constants for a biomass model compound (cellulose) pyrolysis and gasification were identified based on a proposed simplified reaction mechanism within a compartment model structure. A laboratory scale reactor was used for the physical experiments containing consecutive fast pyrolysis and gasification stages using alkali metal (K) containing feedstock, which has a significant effect on the cellulose pyrolysis and gasification. The detailed model was implemented in MATLAB/Simulink environment, and the unknown kinetic parameters were identified based on experimental data. The model was validated based on measurement data, and a good agreement was found. Based on the validated first principle model the optimal parameters were determined as 0.15 mL/min steam flow rate, and 4% K content.

关键词： biomass pyrolysis     kinetic parameter identification     compartment modelling     optimisation    

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Joint slip investigation based on finite element modelling verified by experimental results on wind turbine

Saleh YAGHOOBI, Ahmad SHOOSHTARI

《结构与土木工程前沿（英文）》 2018年 第12卷 第3期   页码 341-351 doi: 10.1007/s11709-017-0393-y

摘要：

Slippage corresponds to the relative displacement of a bolted joint subjected to shear loads since the construction clearance between the bolt shank and the bolthole at assembly can cause joint slip. Deflections of towers with joint slippage effects is up to 1.9 times greater than the displacements obtained by linear analytical methods. In this study, 8 different types of joints are modelled and studied in the finite element program, and the results are verified by the experimental results which have been done in the laboratory. Moreover, several types of joints have been modelled and studied and load-deformation curves have also been presented. Finally, joint slip data for different types of angles, bolt diameter and bolt arrangements are generated. Thereupon, damping ratios (z) for different types of connections are reported. The study can be useful to help in designing of wind turbine towers with a higher level of accuracy and safety.

关键词： Joint slip     cyclic loading     Finite element modelling     Experimental joint behavior     damping ratios (   

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Leaching toxicity characteristics of municipal solid waste incineration bottom ash

Khamphe PHOUNGTHONG,Yi XIA,Hua ZHANG,Liming SHAO,Pinjing HE

《环境科学与工程前沿（英文）》 2016年 第10卷 第2期   页码 399-411 doi: 10.1007/s11783-015-0819-5

摘要： The continuously increasing production of municipal solid waste incineration bottom ash (MSWIBA) has promoted its utilization as construction material and raised environmental concern. The physico-chemical properties and leaching behavior of MSWIBA were studied, and ecotoxicological testing using a luminescent bacterium bioassay was performed to assess the ecological pollution risks associated with its leached constituents. The MSWIBA was leached by two types of leachants, H SO /HNO and HAc solution, at different liquid to solid ratios and contact times. The concentrations of heavy metals and anions in the leachates were analyzed. Multivariate statistical analyses, including principle component analysis, Pearson's correlation analysis and hierarchical cluster analysis, were used to evaluate the contributions of the constituents to the toxicity ( ) of the MSWIBA leachate. The statistical analyses of the ecotoxicological results showed that the Ba, Cr, Cu, Pb, F and total organic carbon (TOC) concentrations were closely correlated with the value, and these substances were the main contributors to the ecotoxicity of the MSWIBA leachate. In addition, the cluster of these variables indicated similar leaching behaviors. Overall, the research demonstrated that the ecotoxicological risks resulting from MSWIBA leaching could be assessed before its utilization, which provides crucial information for the adaptation of MSWIBA as alternative materials.

关键词： Municipal solid waste incineration     bottom ash     alternative material     leaching tests     toxicity     Vibrio qinghaiensis (Q67)    

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标题 作者 时间 类型 操作

The influence of curing conditions on the mechanical properties and leaching of inorganic polymers made

Remus I. Iacobescu, Valérie Cappuyns, Tinne Geens, Lubica Kriskova, Silviana Onisei, Peter T. Jones, Yiannis Pontikes

期刊论文

Sequence of the main geochemical controls on the Cu and Zn fractions in the Yangtze River estuarine sediments

Shou ZHAO,Dongxin WANG,Chenghong FENG,Ying WANG,Zhenyao SHEN

期刊论文

Characteristics of the stabilized/solidified municipal solid wastes incineration fly ash and the leaching

Yan SHAO,Haobo HOU,Guangxing WANG,Sha WAN,Min ZHOU

期刊论文

Assessment of leaching behavior and human bioaccessibility of rare earth elements in typical hospital

Chunfeng Wang, Guanfei Chen, Yanchen Zhu, Dan Yao, Wanfeng Wang, Lianjun Wang

期刊论文

Understanding coupled factors that affect the modelling accuracy of typical planar compliant mechanisms

Guangbo HAO,Haiyang LI,Suzen KEMALCAN,Guimin CHEN,Jingjun YU

期刊论文

Investigation of Cu leaching from municipal solid waste incinerator bottom ash with a comprehensive approach

Jun YAO, Wenbing LI, Fangfang XIA, Jing WANG, Chengran FANG, Dongsheng SHEN

期刊论文

Reinforcement of the two-stage leaching of laterite ores using surfactants

Peiyu Zhang, Hairui Wang, Jingcheng Hao, Jiwei Cui

期刊论文

Oxidative leaching kinetics of molybdenum-uranium ore in H

T. A. Lasheen, M. E. El-Ahmady, H. B. Hassib, A. S. Helal

期刊论文

3D fracture modelling and limit state analysis of prestressed composite concrete pipes

Pengfei HE, Yang SHEN, Yun GU, Pangyong SHEN

期刊论文

铜阳极泥预处理连续加压酸浸工艺开发研究

王吉坤,冯桂林

期刊论文

ANN-based empirical modelling of pile behaviour under static compressive loading

Abdussamad ISMAIL

期刊论文

Leaching of aluminum from coal spoil by mechanothermal activation

Xiaoxue SUN,Yuzhu SUN,Jianguo YU

期刊论文

Kinetic-compartmental modelling of potassium-containing cellulose feedstock gasification

Attila Egedy, Lívia Gyurik, Tamás Varga, Jun Zou, Norbert Miskolczi, Haiping Yang

期刊论文

Joint slip investigation based on finite element modelling verified by experimental results on wind turbine

Saleh YAGHOOBI, Ahmad SHOOSHTARI

期刊论文

Leaching toxicity characteristics of municipal solid waste incineration bottom ash

Khamphe PHOUNGTHONG,Yi XIA,Hua ZHANG,Liming SHAO,Pinjing HE

期刊论文